Carbon and oxygen K-edge photoionization of the CO molecule
โ Scribed by M. Domke; C. Xue; A. Puschmann; T. Mandel; E. Hudson; D.A. Shirley; G. Kaindl
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 562 KB
- Volume
- 173
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
High-resolution, high-intensity photoionization studies were performed near the carbon and oxygen K-edges of gas-phase CO. At least 37 absorption lines were resolved at the carbon K-edge, and new information was obtained about the x*, Rydberg, and double-excitation resonances, including Rydberg states up to n= 7 and vibrational transitions up to u' = 3. Vibrational structure in oxygen is Is-%* and Rydberg states was resolved for the first time. The derived molecular structure parameters are consistent with the Zt 1 approximation. High-resolution, high-intensity core-level photoabsorption promises new opportunities in vibrational state-to-state chemistry and surface science.
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