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Carbon and oxygen K-edge photoionization of the CO molecule

โœ Scribed by M. Domke; C. Xue; A. Puschmann; T. Mandel; E. Hudson; D.A. Shirley; G. Kaindl


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
562 KB
Volume
173
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


High-resolution, high-intensity photoionization studies were performed near the carbon and oxygen K-edges of gas-phase CO. At least 37 absorption lines were resolved at the carbon K-edge, and new information was obtained about the x*, Rydberg, and double-excitation resonances, including Rydberg states up to n= 7 and vibrational transitions up to u' = 3. Vibrational structure in oxygen is Is-%* and Rydberg states was resolved for the first time. The derived molecular structure parameters are consistent with the Zt 1 approximation. High-resolution, high-intensity core-level photoabsorption promises new opportunities in vibrational state-to-state chemistry and surface science.


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