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Carbon-13 spectra of some insect pheromones and related compounds of the 6-8-dioxabicyclo (3.2.1)octane system

✍ Scribed by Glenn T Pearce; William E Gore; Robert M Silverstein

Book ID
103188096
Publisher
Elsevier Science
Year
1977
Weight
695 KB
Volume
27
Category
Article
ISSN
0022-2364

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octanes, prepared from (+)-tartaric acid, were converted by means of an organoaluminium reagent Et2AlSPh into the pyranoid monothioacetals, which were utilized via the successive thioacetalization to the synthesis of the insect pheromones (+)-disparlure and (-)-(2S,3S)-octanediol.