## Abstract The ^13^C NMR spectra of leonurine hydrochloride and thirteen of its analogues in DMSO‐__d__~6~ have been analyzed. Changes in the aromatic substituents have no significant effect on the chemical shifts of the side chain methylene carbons indicating that they do not influence the confor
Carbon-13 nuclear magnetic resonance studies of thiocarbamates, S-oxides and S,S-dioxides
✍ Scribed by C. K. Tseng; D. J. Bowler
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 263 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The ^13^C NMR spectra of four thiocarbamates and their corresponding S‐oxides and S, S‐dioxides are reported. Both β~SO~ and β effects are deshielding and range from 20.44 to 21.68 ppm. The β~SO~′ effects are slightly deshielding (0.20 ∼ 0.0.77 ppm). The β′ effects, on the contrary, are shielding and range from −6.54 to −6.98 ppm. The γ′, δ′, ξ′, and ζ′ effects are also discussed.
📜 SIMILAR VOLUMES
## Abstract The ^13^C NMR spectra of 2‐halopicolines, 2‐halopicoline __N__‐oxides and 2‐halo‐4‐nitropicoline __N__‐oxides were recorded and their chemical shifts assigned. The influence of the electronic properties of the substituents on the direction of the chemical shifts is discussed.
## Abstract Samples of dimer and trimer derived from chiral propylene oxide, having head‐to‐tail linkages were prepared using an aluminium complex of a Schiff's base and were studied by means of ^13^C NMR spectroscopy. Based on these spectroscopic data and on J‐Modulated Spin Echo Technique (JMSET)