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Carbon-13 nuclear magnetic resonance of the azomethine group. II—(II.II) conjugation and twist angles

✍ Scribed by A. Solladié-Cavallo; G. Solladié

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
267 KB
Volume
10
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Torsional angles in some mono‐substituted conjugated benzenes were determined from the chemical shift of the para carbons. Similar results were obtained from ketones and imines, and the torsional angles increase, as expected, with steric hindrance. It is possible to assign a syn or anti stereochemistry for the imines from the value of the torsional angle.

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