## Abstract Carbon‐13 NMR signal assignment of a number of polyoxygenated triterpenes of the olean‐12‐ene and urs‐12‐ene series, carried out by considering the changes in chemical shift produced by the change of oxygenation pattern(s), and using methyl oleanolate as a model, are reported.
Carbon-13 NMR spectroscopy of some Strychnos alkaloids. Part 2
✍ Scribed by R. Verpoorte; T. A. van Beek; R. L. M. Riegman; P. J. Hylands; N. G. Bisset
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 348 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
London SW3 6LX, UK CNMR data for a series of natural and semi-synthetic ar-hydroxy-and -metho--substituted Strychnos alkaloids are presented and are used to determine substituent-induced chemical shift (SCS) values for the various substitution patterns. 13 R1 H R3 20 alkaloids have been examined. The full range of com-R* cH3 R2 0 5 H 10 19 Rp-&)
d3 N H '16h 20
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