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Carbon-13 n.m.r. spectroscopy of some Strychnos alkaloids

✍ Scribed by R. Verpoorte; P. J. Hylands; N. G. Bisset

Book ID: 102950531
Publisher: John Wiley and Sons
Year: 1977
Tongue: English
Weight: 521 KB
Volume: 9
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270091004

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✦ Synopsis

Abstract

^13^C N.m.r. spectra have been determined for strychnine and a series of fourteen derivatives. The assignments are based on previously established data and on off‐resonance decoupled spectra. The shifts resulting from the alterations in molecular structure are discussed and explained, in part, as a consequence of conformational changes. This detailed study indicates that changes are required in some previously published assignments.

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