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Carbon-13 NMR spectroscopic study of the application of the "tool of increasing electron demand" to the 7-aryl-1-norbornenyl, 7-aryl-7-norbornyl, 2-aryl-2-bicyclo[2.1.1]hexyl, 1-aryl-1-cyclobutyl, and 3-aryl-3-nortricyclyl cations

✍ Scribed by Olah, George A.; Berrier, Arthur L.; Arvanaghi, Massoud; Prakash, G. K. Surya


Book ID
120554189
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
855 KB
Volume
103
Category
Article
ISSN
0002-7863

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The reaction of 2,6-diarylidenecyclohexanones with hydrazine hydrate in glacial acetic acid resulted in the formation of diastereomers of (E)-2-acetyl-3-aryl-7-arylidene-3,3a,4,5,6,7-hexahydroindazoles. The relative conÐgurations of these diastereomers were unambiguously assigned using 1H and 13C NM