## Abstract Carbon‐13 NMR signal assignment of a number of polyoxygenated triterpenes of the olean‐12‐ene and urs‐12‐ene series, carried out by considering the changes in chemical shift produced by the change of oxygenation pattern(s), and using methyl oleanolate as a model, are reported.
Carbon-13 NMR spectra of some tetra- and pentacyclic triterpenoids
✍ Scribed by S. A. Knight
- Book ID
- 102951800
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 866 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The carbon‐13 NMR spectra of lanosta‐8‐en‐3β‐ol, lanosta‐8, 24‐dien‐3β‐ol, lanosta‐7,9(11)‐dien‐3β‐ol, lanostan‐3β‐ol, eupha‐8‐en‐3β‐ol, eupha‐8,24‐dien‐3β‐ol, ursa‐12‐en‐3β‐ol (α‐amyrin) and oleana‐12‐en‐3β‐ol (β‐amyrin) have been obtained and completely assigned. The results of this study provide chemical shift data for methyl, methylene, methine and quaternary carbon atoms in tetra‐ and pentacyclic triterpenoid spectra. The carbon‐13 NMR spectrum of a triterpenoid provides a unique fingerprint for the molecule.
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