## Abstract Carbon‐13 NMR signal assignment of a number of polyoxygenated triterpenes of the olean‐12‐ene and urs‐12‐ene series, carried out by considering the changes in chemical shift produced by the change of oxygenation pattern(s), and using methyl oleanolate as a model, are reported.
Carbon-13 NMR spectra of some tetra- and pentacyclic triterpene methyl ethers
✍ Scribed by J. W. Blunt; M. H. G. Munro
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 194 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The carbon‐13 NMR spectra have been recorded for representatives of three previously unexamined classes of pentacyclic triterpenes—lupanes, fernanes and arboranes. In addition to the spectra of lupeol methyl ether, cylindrin and arundoin, the spectra of a number of other triterpene methyl ethers are also recorded. The effect of methyl ether formation on the shilding values for carbons in the 3β‐hydroxy‐4,4‐dimethyl‐ ring A system is defined.
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13C NMR signals were assigned for a series of C-6 rnethylated steroids related to 5 acholestane, and the substituent effect of methyl groups at C-6 on the shielding data is discussed.
## Abstract Carbon‐13 signal assignments of the labdane diterpenoids phlogantholide‐A, its diacetate and isophlogantholide‐A are reported. The assignments of the ^13^C NMR signals of 14‐deoxyandrographolide and its diacetate, made earlier, have now been confirmed by lanthanide shift studies on the