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Carbon-13 NMR spectra of saturated heterocycles: VIII—tetrahydrofurans and 1,3-dioxolanes

✍ Scribed by Ernest L. Eliel; V. Satyanarayana Rao; K. Michal Pietrusiewicz

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
595 KB
Volume
12
Category
Article
ISSN
0749-1581

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The ^13^C NMR spectra of 17 methyl‐ and ethyl‐substituted tetrahydrofurans and 58 alkyl‐ and aryl‐ substituted 1,3‐dioxolanes are reported. For the cases in which substituents recur, additive substituent parameters are calculated and compared with similar parameters in cyclopentanes and in 6‐membered rings. Considering the conformational flexibility of 5‐membered ring systems, additivity of the parameters is surprisingly good.

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