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Carbon-13 NMR spectra of heterocycles. Sultones and sultams.

✍ Scribed by M. Kausch; H. Dürr; S. H. Doss

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
303 KB
Volume
10
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^13^C NMR spectra of 1,3‐propanesultam, 2,4‐butanesultam, 1,4‐butanesultam, 1,3‐propanesultone and 1,4‐butanesultone, as well as some of their unsaturated analogs 2,4‐dimethylbuta‐1,3‐diene‐1,4‐sultone and 2,4‐dimethylbuta‐1,3‐diene‐1,4‐sultam, have been recorded. The observed chemical shift data for the sultams and sultones can be explained mainly on the basis of inductive effects. The δ values of the dienesultone and the dienesultam are mainly affected by M‐effects. ^1^H NMR as well as mass spectra have.

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