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Carbometalation of .alpha.,.omega.-Dienes and Olefins Catalyzed by Zirconocenes

✍ Scribed by Shaughnessy, Kevin H.; Waymouth, Robert M.


Book ID
126051628
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
239 KB
Volume
117
Category
Article
ISSN
0002-7863

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Hydrosilylation of olefins and dehydroge
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Divalent lanthanide-imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl-and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, under similar conditions.