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Carbocationic polymerizations in supercritical carbon dioxide

✍ Scribed by Tibor Pernecker; Joseph P. Kennedy


Book ID
105022132
Publisher
Springer
Year
1994
Tongue
English
Weight
423 KB
Volume
32
Category
Article
ISSN
0170-0839

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Radical homopolymerizations and copolymerizations of 3-[tris(trimethylsilyloxy)silyl]propyl methacrylate (SiMA) in supercritical CO 2 were investigated. The homopolymer was obtained in CO 2 with a good yield. It was essentially insoluble in pure CO 2 at less than 500 bar at 65 Β°C but was soluble in