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ChemInform Abstract: Polymerizations in Supercritical Carbon Dioxide

✍ Scribed by Jonathan L. Kendall; Dorian A. Canelas; Jennifer L. Young; Joseph M. DeSimone


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
30
Category
Article
ISSN
0931-7597

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Radical homopolymerizations and copolymerizations of 3-[tris(trimethylsilyloxy)silyl]propyl methacrylate (SiMA) in supercritical CO 2 were investigated. The homopolymer was obtained in CO 2 with a good yield. It was essentially insoluble in pure CO 2 at less than 500 bar at 65 Β°C but was soluble in