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Carbene Fragmentation in the Bicyclo[3.1.0]hexyl System: Disconnecting the Trishomocyclopropenyl Cation

โœ Scribed by Moss, Robert A.; Fu, Xiaolin


Book ID
125900642
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
59 KB
Volume
6
Category
Article
ISSN
1523-7060

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A recent report (1) describing the nature of the 2-bicyclo[3.1.0]hexyl cation formed in the solvolysis of epimeric 2-chlorobicyclo[3.1.0]hexanes prompts us to report our work on this system which provides an explanation for the small difference in rate between endo-and exo-isomers. Endo-(Ib) and ex