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Carbamazepine oxidation catalyzed by manganese porphyrins: Effects of the β-bromination of the macrocycle and the choice of oxidant

✍ Scribed by Dayse CarvalhoDa-Silva; Tatiana Cristina Oliveira Mac Leod; André Luiz de Faria; Joicy Santamalvina dos Santos; Maria Eliza Moreira Dai de Carvalho; Júlio Santos Rebouças; Ynara Marina Idemori; Marilda das Dores Assis

Book ID
113459340
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
537 KB
Volume
408
Category
Article
ISSN
0926-860X

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Regioselective oxidations of equilenin d
Regioselective oxidations of equilenin derivatives catalyzed by a rhodium(III) porphyrin complex—contrast with the manganese(III) porphyrin
✍ Jerry Yang; Ronald Breslow 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 90 KB

Equilenin acetate and dihydroequilenin acetate were oxidized with iodosobenzene and a rhodium(III) porphyrin catalyst. The selectivity of the reactions differs from that with the corresponding Mn(III) catalyst, or from that of free radical chain oxidation.