𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Carbamates of cellulose bonded on silica gel: Chiral discrimination ability as HPLC chiral stationary phases

✍ Scribed by Laureano Oliveros; Antonio Senso; Pilar Franco; Cristina Minguillón

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
124 KB
Volume
10
Category
Article
ISSN
0899-0042

No coin nor oath required. For personal study only.

✦ Synopsis

Four cellulose mixed 10-undecenoate/carbamate derivatives, simultaneously bearing 10-undecenoyl and variously substituted phenylaminocarbonyl groups, were chemically bonded on allylsilica gel. The study of the effect of these substitutions on the performance of the resulting chiral supports, and a comparison with the recently described 10-undecenoate/3,5-dimethylphenylcarbamate derivative, are presented. In this study heptane/2-propanol or heptane/chloroform mixtures were used as mobile phases.

📜 SIMILAR VOLUMES

Benzoates of cellulose bonded on silica
Benzoates of cellulose bonded on silica gel: Chiral discrimination ability as high-performance liquid chromatographic chiral stationary phases
✍ Laureano Oliveros; Antonio Senso; Cristina Minguillón 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 220 KB 👁 2 views

In order to generalize the recently described method for the insolubilization of polysaccharide derivatives to benzoates of cellulose, five mixed 10undecenoate/benzoates of this polysaccharide have been prepared and linked to allyl silica gel by means of a radical reaction. The chiral recognition ab

HPLC enantioseparation on cellulose tris
HPLC enantioseparation on cellulose tris(3,5-dimethylphenylcarbamate) as a chiral stationary phase: Influences of pore size of silica gel, coating amount, coating solvent, and column temperature on chiral discrimination
✍ Eiji Yashima; Pennapa Sahavattanapong; Yoshio Okamoto 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 444 KB 👁 2 views

Cellulose tris(3,5dimethylphenylcarbamate) (CDMPC) was coated on largepore silica gels and used as a chiral stationary phase (CSP) for high-performance liquid chromatographic separation of enantiomers. The influences of pore size of silica gel, coating amount of CDMPC, coating solvent, and column te

Diphenylethanediamine (DPEDA) as chiral
Diphenylethanediamine (DPEDA) as chiral selector: VII. Efficient HPLC resolution of a series of underivatized diarylcarbinols on a chiral stationary phase based on C5-amide-bonded N-3,5-dinitrobenzoyl-DPEDA
✍ Norbert M. Maier; Georg Uray 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 335 KB 👁 2 views

Fast and efficient baseline separation of asymmetrically substituted diarylmethanols and 1,ldiarylethanols was achieved on an endcapped, amidelinked N-3,Minitrobenzoylated, (R,R)-1,2diphenyl-l,2-ethanediaminederived chiral stationary phase (CSP) . Optimal enantioselectivities on this CSP were obtain