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Captodative olefins in normal and inverse Diels-Alder Reactions

✍ Scribed by Jürgen Mertes; Jochen Mattay

Publisher
John Wiley and Sons
Year
1988
Tongue
German
Weight
412 KB
Volume
71
Category
Article
ISSN
0018-019X

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✦ Synopsis

Part 3 of 'Thermal Reactions of Donor-Acceptor Systems'. Part 2: [I].

Taken in part from the diploma thesis (KWTH 1986) and from the planned Ph. D. thesis. The interactions of both pairs of frontier orbitals have to be considered in the so-called neutral (type 11) LXels-Alder reaction. Examples, however, are not frequent [2].

No formation of products from 8 and 2 has been observed under normal pressure at 80".

The crude product contains two further 1 : 1 adducts (0.9 and 1.4%, resp.) according to GC/MS analyses

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