Can mass dissociation patterns of transition-metal complexes be predicted from electrochemical data?

The Energy Profile of Proton Transfer fr

The Energy Profile of Proton Transfer from Brønsted Acids to Terminal Hydrides in Transition Metal Complexes Can Be Estimated by Combining in situ IR and NMR Spectroscopy

✍ Natalia V. Belkova; Ekaterina V. Bakhmutova; Elena S. Shubina; Claudio Bianchini 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 229 KB 👁 1 views

The enthalpy and entropy changes relative to the stepwise reaction of [(triphos)Re(CO) 2 H] with perfluoro-tert-butyl alcohol in CH 2 Cl 2 to give first the hydrogen-bonded adduct [(triphos)Re(CO) 2 H•••HOC(CF 3 ) 3 ] and then the stable non-[a] A. N.