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Calorimetric determination of the enthalpy change for the binding of methyl orange to poly(vinylpyrrolidone) in aqueous solution

✍ Scribed by I. Sardharwalla; J.B. Lawton

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
611 KB
Volume
26
Category
Article
ISSN
0032-3861

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Calorimetric measurement of enthalpy cha
Calorimetric measurement of enthalpy change in the isothermal helix–coil transition of poly(L-ornithine) in aqueous solution
✍ Yi-Chang Fu; Harold E. Van Wart; Harold A. Scheraga πŸ“‚ Article πŸ“… 1976 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 994 KB

The enthalpy change associated with the isothermal pH-induced uncharged coil-to-helix transition AH; in poly(L-ornithine) in 0.1 N KCl has been determined calorimetrically to be -1530 f 210 and -1270 f 530 cal/mol a t loo and 25OC, respectively. Titration data provided information about the state of