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Calculations of Electrostatic Interactions and p K a s in the Active Site of Escherichia coli Thioredoxin †,‡

✍ Scribed by Dillet, Valérie; Dyson, H. Jane; Bashford, Donald

Book ID
127020883
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
135 KB
Volume
37
Category
Article
ISSN
0006-2960

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The spin-coupling model of the {[Fe4S4]-siroheme} center of the active site of sulfite reductase is developed. The tetmmer-siroheme coupling 2JthS j -s h results in the induced paramagnetism of individual ions of the Fe/S tetramer which = ~ \_\_ 33/j .j. provides non-zero effective hyperfine consta