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Calculation of the optimal orientation of methyl groups in crystals

✍ Scribed by N. N. Afonia; P. M. Zorkii


Book ID
104924498
Publisher
SP MAIK Nauka/Interperiodica
Year
1976
Tongue
English
Weight
266 KB
Volume
17
Category
Article
ISSN
0022-4766

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Rotational dynamics of the methyl group
✍ L. Soulard; F. Fillaux; G. Braathen; N. Le CalvΓ©; B. Pasquier πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 528 KB

Raman spectra below 150 cm-' of the 4-methyl pyridine crystal, and its deuterated derivative (d,), at various temperatures from 276.8 K (melting point) to 5 K are presented and vibrational assignments proposed. Three crystal phases are observed between 5-100 K (III), loo-254 K (II) and 254-276.8 K (