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Calculation of restricted rotational states in the methyl group

✍ Scribed by Y. Ozaki


Book ID
106024842
Publisher
Springer
Year
2002
Tongue
English
Weight
66 KB
Volume
74
Category
Article
ISSN
1432-0630

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Rotational dynamics of the methyl group
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Raman spectra below 150 cm-' of the 4-methyl pyridine crystal, and its deuterated derivative (d,), at various temperatures from 276.8 K (melting point) to 5 K are presented and vibrational assignments proposed. Three crystal phases are observed between 5-100 K (III), loo-254 K (II) and 254-276.8 K (

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Methane molecules in a square lattice perform hindered rotation due to the molecular interaction. First, the one-body term in the interaction gives the new pattern of rotational energy level scheme. In the case of strong interaction, this scheme becomes similar to tunneling levels calculated from th