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Calculation of the binary diffusion second virial coefficient

โœ Scribed by R.D. Olmsted; G.R. Staker; R.D. Trengove; P.J. Dunlop


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
220 KB
Volume
87
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Deport~rrcm ofP/fj tical md I~ro~wrrrc Chemistry Um ernt_v of .-ldelaide -ldelarde. Sour/r Austrah 5001 Rccclrcd I Novcmbcr 198 1. m tin31 form II January 1982 Calcularions of rhe iirst density corrccnon IO the binary dlfiuslon coeificlrnt arc prcsrnted ior sewal matures. These calculanons arc bacd on the clxs~cal kmcrlc theory ior matu:cs dcvelopcd by Benncrl and Curllss. The theoretIcal predlclions agree MU wth c\pcnmaral dala.


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Regge representation of the second viria
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The Beth-Uhlenbeck formula is rederived using the notion of symmetrized and anti-symmetrized partition function introduced by Lee and Yang. By applying the method of complex angular momentum the summation of the phase shifts appearing in the formula is converted into an integral form. Consequently,

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A previous method for calculating the second virial coefficients of pure compounds and mixtures is revised. The two empirical constants of a semi-theoretical relation are related to the reduced second virial coefficient values of a pure compound calculated at the normal boiling temperature and at th

Excess and interaction second virial coe
โœ T.N. Bell; P.J. Dunlop ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 276 KB

Excess and intkcfion second vhial coefficients h&e been measured over the temperature range 293-321 K For the systems He-N2, He-CO\*, He-NZO, Hea, He-SFe, BE are e&mated to have an accuracy of 0.3 cm3 mol-\* He-CFa and Ar-SFe. The excess second virial coefficients