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Calculation of the bandshape of vibronically-allowed d-d transitions

✍ Scribed by Hans J. Kupka

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
310 KB
Volume
47
Category
Article
ISSN
0009-2614

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✦ Synopsis

Absorption and emission line shapes are calculated in transition-metal ions. It is shown that for the case of "strong vibronic coupled" electronic states the emission or absorption bands are of gaussian shape.

πŸ“œ SIMILAR VOLUMES

Calculation of the vibronic bandshape of
Calculation of the vibronic bandshape of the 2Eg→4A2g phosphorescence in 3d3 complexes
✍ J. Kupka πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 688 KB

CalcuIations of the vibronic bandshape of the 'E o -+ 4Azg transition in octahedral 3d3 complexes are presented. The vibrcmic intensity is expressed in terms of lore&an functions centered around the fundamental odd vibrations of the complex in respect to the 0-O line and weighted by coupling coeffic