Calculation of liquid junction potentials
β Scribed by Harper, Harry W.
- Book ID
- 123618009
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 820 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Junction potenuals for KCl(4M)IIX where X IS one of N&l, L&l, NaOH, HCl, L@04, Ms(NO,h, L&l, ran8mg m concentration from 0 001 to 4 M have been calculated at 0,25, 100Β°C by usmg the emulation and numerical methods of Parts I and II [J. Bagg, Ekctrochim Acta 3!!, 361, 367 (1990)] Junction pot@& range
A numerical method has been used to simulate the junction Z (0.001-6 M) (( KCI (4 M), where Z is (a) HCI or an alkali halide with an ion in common with KC1 or (b) CaCI,, LaCI,, or K,SO,. By applying diffusion equations to this simulation the ionic concentration profiles have been determined. The dif