## Abstract The technique of SPPLP EPR, which is singleโpulse pulsedโlaser polymerization (SPPLP) in conjunction with electron paramagnetic resonance (EPR) spectroscopy, is used to carry out a detailed investigation of secondary (chainโend) radical termination of acrylates. Measurements are perform
Calculation method of molecular weight averages in polymerization with chain-length-dependent termination
โ Scribed by P. Rivero
- Book ID
- 106438176
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 147 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1022-9760
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Using a new simulation procedure in which each individual propagation step is subjected to a Poisson process it was proved that in case of chainโlength dependent termination the apparent rate of propagation no longer coincides with the true one. This is caused by the polydispersity of t
A~traet A numeric solution is developed for a kinetic scheme involving chain length dependent termination (by disproportionation) and chain transfer on the basis of the harmonic and the geometric mean approximation for the two radicals involved in the termination process. In addition, solutions in t
## Abstract Kinetic simulations using the composite __k__~t~ model allows a better understanding of the effects of the persistent radical affecting ATRP or for that matter any activationโdeactivation system. It also provides a better fit to experimental data in either bulk or solution conditions fo