𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chain-length-dependent termination rate constant: Effect on molecular weight distributions formed by pulsed laser radical polymerization

✍ Scribed by Anatolij N. Ntkitin; Alexander V. Evseev


Book ID
118285155
Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
981 KB
Volume
6
Category
Article
ISSN
1022-1344

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Postpolymerization effect on molecular w
✍ Anatolij N. Nikitin πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 498 KB

## Abstract The postpolymerization effect on molecular weight distribution (MWDs) and on the Pulsed Laser Polymerization (PLP) technique for evaluation of kinetic constants is investigated. General expressions for moments are derived for a polymerization scheme that contains the reactions of chain

Chain-length dependent termination in pu
✍ Oskar Friedrich Olaj; Andreas Kornherr; Gerhard Zifferer πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 613 KB

The correct (event-weighted) average of k,, (k,), has been calculated from simulation data for pseudostationary laser-induced polymerization for a kinetic scheme with chain-length dependent termination and compared to the average k, which is obtained by employing the formal procedures, originally de

Kinetics of free-radical polymerization
✍ Anatolij N. Nikitin; Alexander V. Evseev πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 216 KB πŸ‘ 2 views

A numerical procedure is developed which allows taking into account the chain length dependence of the termination and propagation constants for calculating molecular weight distributions (MWDs) formed under free-radical polymerization initiated by an arbitrary sequence of laser pulses. The law whe

Chain-length dependent termination in pu
✍ Oskar Friedrich Olaj; Andreas Kornherr; Gerhard Zifferer πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 528 KB

## Abstract The correct (event weighted) average of __k__~t~, γ€ˆ__k__~t~〉, has been calculated for pseudostationary laser‐induced polymerization for a kinetic scheme with chain‐length dependent termination and compared to the average __kΜ„__~t~ obtained by formally solving for __k__~t~ the expression