## Abstract The postpolymerization effect on molecular weight distribution (MWDs) and on the Pulsed Laser Polymerization (PLP) technique for evaluation of kinetic constants is investigated. General expressions for moments are derived for a polymerization scheme that contains the reactions of chain
Chain-length-dependent termination rate constant: Effect on molecular weight distributions formed by pulsed laser radical polymerization
β Scribed by Anatolij N. Ntkitin; Alexander V. Evseev
- Book ID
- 118285155
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 981 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1022-1344
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π SIMILAR VOLUMES
The correct (event-weighted) average of k,, (k,), has been calculated from simulation data for pseudostationary laser-induced polymerization for a kinetic scheme with chain-length dependent termination and compared to the average k, which is obtained by employing the formal procedures, originally de
A numerical procedure is developed which allows taking into account the chain length dependence of the termination and propagation constants for calculating molecular weight distributions (MWDs) formed under free-radical polymerization initiated by an arbitrary sequence of laser pulses. The law whe
## Abstract The correct (event weighted) average of __k__~t~, γ__k__~t~γ, has been calculated for pseudostationary laserβinduced polymerization for a kinetic scheme with chainβlength dependent termination and compared to the average __kΜ__~t~ obtained by formally solving for __k__~t~ the expression