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Calculated structures and electrostatic potentials of some 1,4-dioxazines and 1,4-dioxadiazines

✍ Scribed by Jane S. Murray; Peter Politzer


Book ID
119117002
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
767 KB
Volume
180
Category
Article
ISSN
0166-1280

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A convenient synthesis of 4-trifluoromet
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## Abstract 1,1,1‐Trifluoroalkane‐2,3‐dione 3‐oximes 1 easily obtainable from aldehyde dimethylhydrazones were reacted with several aldehydes and ketones in the presence of acetic acid to afford 4‐trifluoromethyl‐4__H__‐[1,5,2]dioxadines 3 in satisfactory yields. When the reaction was carried out i