Calcium-mediated stereoselective reduction of α,β-epoxy ketones
✍ Scribed by Forkel, Nina V.; Henderson, David A.; Fuchter, Matthew J.
- Book ID
- 126231476
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- French
- Weight
- 707 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0040-4039
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Erythro-a, B-epoxy alcohols were prepared in high stereoselectivity by zinc borohydride reduction of the corresponding a, B-epoxy ketones regardless of the substituents on the epoxide ring. Epoxidation of the ally1 alcohols (L) with tert-butyl hydroperoxide catalyzed by VO(acac)2 was reported to giv