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Calcium-Catalyzed Cyclopropanation

✍ Scribed by Haven, Tobias; Kubik, Grzegorz; Haubenreisser, Stefan; Niggemann, Meike

Book ID
119991566
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
641 KB
Volume
52
Category
Article
ISSN
0044-8249

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Metalloporphyrin catalyzed asymmetric cy
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Asymmetric cyclopropanation of styrene by an enantiopure carbenoid under catalysis by simple metalloporphyrins was found to be much more efficient and selective than the alternative approach, the combination of metal complexes of enantiopure porphyrins and a non-chiral diazoester.