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Calcium-Catalyzed Cycloisomerization of Enynes

✍ Scribed by Meyer, Vera J.; Fu, Liang; Marquardt, Fabian; Niggemann, Meike


Book ID
120564344
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
224 KB
Volume
355
Category
Article
ISSN
1615-4150

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Gold (I) complexes generated from a mixture of gold and silver salts were found to be highly reactive for the cycloisomerization reactions of boronated enynes. Both alkynyl pinacol boronates and alkenyl pinacol boronates were tolerated, affording products in moderate to high yields. Interestingly, t