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Cadmium(II) halide complexes of pyrazine

✍ Scribed by Rosa D. Bailey; William T. Pennington

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
449 KB
Volume
16
Category
Article
ISSN
0277-5387

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πŸ“œ SIMILAR VOLUMES

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We have recently shown [ 1 ] how significant vanatlon in the structures of HgX2(PR3) complexes [l-3 ] can be rationalised in terms of the varying u-donor strengths of the PRs ligands coupled with the tendency for mercury(H) towards linear co-ordination. Cadmium shows no such preference for digonal g

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DiaquaΒ­bis[5-(pyrazin-2-yl)tetraΒ­zolato]cadmium(II)
✍ Song, Wen-Dong ;Xi, Dan-Li πŸ“‚ Article πŸ“… 2006 πŸ› International Union of Crystallography 🌐 English βš– 252 KB

The title complex, [Cd(C 5 H 3 N 6 ) 2 (H 2 O) 2 ], possesses a crystallographically imposed inversion centre. The Cd II atom is coordinated by four N atoms [Cd-N = 2.2794 (16) and 2.4155 (16) A ˚] from two 5-(pyrazin-2-yl)tetrazolate ligands and two water molecules [Cd-O = 2.263 (2) A ˚] in a disto