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Cadmium mercury seleno­cyanate, CdHg(SeCN)4

✍ Scribed by Sun, Hai-Qing ;Yu, Wen-Tao ;Yuan, Duo-Rong ;Wang, Xin-Qiang ;Xue, Gang

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
141 KB
Volume
61
Category
Article
ISSN
1600-5368

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MnHg(SeCN) 4 has a three-dimensional network in which slightly distorted MnN 4 and HgSe 4 tetrahedra (symmetry 4) are connected by -SeCN-bridges.

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The title compound, CoHg(SeCN) 4 , was obtained by selfassembly. X-ray crystal structure analysis reveals that it has an extended three-dimensional network structure in which the slightly distorted CoN 4 and HgSe 4 tetrahedra are connected by -SeCN-bridges. The Hg and Co atoms lie on positions of 4

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## Abstract The title structure, [Me~2~Im][Cd(SeCN)~3~] (Me~2~Im = __N,N__′‐dimethylimidazolium), comprises triply bridged one‐dimensional cadmium‐selenocyanate chains in which the cadmium atoms are octahedrally coordinated within 3__Se__3__N__ geometries. Copyright © 2003 John Wiley & Sons, Ltd.