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Ca(AsF3)(AsF6)2: The First Alkaline Earth Metal Cation Coordinated to AsF3.

✍ Scribed by Melita Tramsek; Boris Zemva


Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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Syntheses, crystal structures and Raman
✍ Matic LozinΕ‘ek; Tina Bunič; Evgeny Goreshnik; Anton Meden; Melita TramΕ‘ek; GaΕ‘pe πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 English βš– 583 KB

In the system BaF 2 /BF 3 /PF 5 /anhydrous hydrogen fluoride (aHF) a compound Ba(BF 4 )(PF 6 ) was isolated and characterized by Raman spectroscopy and X-ray diffraction on the single crystal. Ba(BF 4 )(PF 6 ) crystallizes in a hexagonal P62m space group with a ΒΌ 10.2251(4) Γ…, c ΒΌ 6.1535(4) Γ…, V ΒΌ 5