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The Polymeric Silver Complexes [Ag{Sn(CN)2}2][AsF6] (n = 3, 4): Stable Coordination Compounds of Dicyanotri- and Dicyanotetrasulfanes

✍ Scribed by Prof. Dr. Herbert W. Roesky; Dipl.-Chem. Thomas Gries; Jürgen Schimkowiak; Priv.-Doz. Dr. Peter G. Jones


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
253 KB
Volume
25
Category
Article
ISSN
0044-8249

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## Abstract The first argentate salt of carborane anion, [{(CH~3~CN)~4~Ag~3~}{Ag(CB~11~I~5~Br~6~)~2~}]~__n__~, was prepared from K~2~[CB~11~I~5~Br~6~] and AgNO~3~ followed by recrystallization from acetonitrile. Single‐crystal X‐ray analyses indicate that the CB~11~I~5~Br~6~^2−^ dianion has a signi