𝔖 Bobbio Scriptorium
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[C6H3(CH3)3][BiCl3] and [C6(CH3)6][BiCl3]2, Arene Complexes of Bismuth with Half-Sandwich and “Inverted” Sandwich Structures

✍ Scribed by Dr. Annette Schier; Dr. Julian M. Wallis; Dr. Gerhard Müller; Prof. Dr. Hubert Schmidbaur


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
362 KB
Volume
25
Category
Article
ISSN
0044-8249

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Trimethylamine-bis(trifluoromethyl) boranes R(CF 3 ) 2 B ´NMe 3 (R = cis/trans-CF 3 CF=CF (1/2), HCºC (3), H 2 C=CH (4), C 2 H 5 (5), C 6 H 5 CH 2 (6), C 6 F 5 (7), C 6 H 5 (8)) react with NEt 3 ´3 HF depending on the nature of R at 155±200 °C under replacement of the trimethylamine ligand to form