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C60CCl4 phase diagram: polythermal behaviour of solvates C60, 12 CCl4 and C60, 2 CCl4

✍ Scribed by Maria Barrio; David O. López; Josep Ll. Tamarit; Henri Szwarc; Siro Toscani; René Céolin

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
279 KB
Volume
260
Category
Article
ISSN
0009-2614

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✦ Synopsis

Polythermal investigation of the C6o-CC14 system resulted in two phase diagrams. The stable one involves two solvates with 1 : 12 and 1 : 2 molar ratios, respectively. A metastable diagram, only showing the 1 : 2 solvate, has been observed. C6o, 12 CCI 4 and C6o, 2 CC14 decompose peritectically at 299 and 402 K, with AH= 15.2 and 61 J g-l, respectively. C6o, 12 CCI 4 is formed with a positive excess volume while C60, 2 CC14 does so with a negative one. The desolvation enthalpy for C6o, 2 CCI 4 and sublimation enthalpy for pure CC] 4 are close.

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