(C5H5)3CoMn2(CO)4(CS)PMe3–A Hetero-Trinuclear Complex with a μ2-C,η1-S Bonded Thiocarbonyl Group
✍ Scribed by Oswald Kolb; Prof. Dr. Helmut Werner
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 219 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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200 MHz, ] toluene, -40°C): 6 = 3 1 . 5 f 1 (a = b); "C('H1 NMR (200 MHz, [Dx]toluene, -40°C): &=(a) 13.41 (s, CCHi), 31.22 (s, C(CH,), 54.22 (s, C(CH3)'), 103.89 (s, C4), 117.94 (s, C5). The signals for C3 and C6 cannot be observed due to their position next to the boron atom. Owing to the poor s
The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th
We thank the European Commission through the HYDROCHEM program (contract HPRN-CT-2002-00176) for support of this work. M.B. thanks the Spanish Ministerio de Educación y Ciencia for a postdoctoral fellowship.