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[(C3Ph3)Ni(μ-Br)3Ni(C3Ph3)](C3Ph3)—A Triple-Decker-like Complex with Triphenylcyclopropenyl as Ligand

✍ Scribed by Dipl.-Chem. Franco Cecconi; Dr. Carlo A. Ghilardi; Dr. Stefano Midollini; Dr. Simonetta Moneti; Dr. Annabella Orlandini


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
239 KB
Volume
25
Category
Article
ISSN
0044-8249

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✦ Synopsis


151 €vperrrn<m/ul procedure-la was synthesized from iron (5.5 g, 98 mmoi)

and toluene (300g) within 2 h by cocondensation at lo-' Pa and -196 C Ethylene (140 g, 5 mmol) was added to the mixture by conden-' ' I are summarized in Scheme I.


📜 SIMILAR VOLUMES


[C3Ph3)Ni(μ-Br)3Ni(C3Ph3)](C3Ph3) – eine
✍ Dipl.-Chem. Franco Cecconi; Dr. Carlo A. Ghilardi; Dr. Stefano Midollini; Dr. S. 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 351 KB

Die hohe thermische und photochemische Labilitat von 2 sowie die Notwendigkeit der gepulsten (14 ns) Megawattleistungen erklaren das Scheitern friiherer Bemiihungen zur Synthese von Triaziridinen (siehe [' -' I). Unsere Befunde sprechen fur die Bildung von 2 durch Mehr-, vermutlich Zweiphotonen-Anr