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[C2O2]+˙ ions of unusual structure

✍ Scribed by Pandolfo, Luciano; Paiaro, Gastone; Catinella, Silvia; Traldi, Pietro

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
306 KB
Volume
31
Category
Article
ISSN
1076-5174

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✦ Synopsis

The structure of the C,O:' ion, obtained by electron impact ionization of C,O,, is reported. A double-focusing instrument was used to carry out metastable ion and collisional spectroscopic studies. Comparison of the data showed that a C,O:' species structurally different from those originating from other precursors is obtained by ionization of C,O,. A four-membered ring is proposed as the possible structure of the C,Of ' ion.

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✍ Ming Wah Wong; Leo Radom 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 650 KB

Ab initio molecular orbital theory using basis sets up to 6-311G\*\*, with electron correlation incorporated via configuration interaction calculations with single and double substitutions, has been used to study the structures and energies of the C,H, monocation and dication. In agreement with rece