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C2-Symmetric bimorpholines as chiral ligands in the asymmetric hydrogenation of ketones

✍ Scribed by Kadri Kriis; Tõnis Kanger; Aleksander-Mati Müürisepp; Margus Lopp

Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
112 KB
Volume
14
Category
Article
ISSN
0957-4166

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✦ Synopsis

Bimorpholine and 3,3%-bimorpholine were used as chiral ligands in Rh-mediated asymmetric hydride transfer reduction of prochiral aromatic ketones affording corresponding alcohols with good ee (up to 75%).

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