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C-Phosphorylation of Azoles in Synthesis of Novel Fused Phosphorus-Containing Heterocycles

✍ Scribed by Alexander M. Pinchuk; Vladimir V. Ivanov; Evgenij V. Zurudnizkii; Alexej O. Pushechnikov; Andrej A. Tolmachev


Publisher
John Wiley and Sons
Year
2003
Weight
52 KB
Volume
34
Category
Article
ISSN
0931-7597

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Enamines 5 , prepared from heterocycles with a methyl group at a-position in respect to ring nitrogen atom 1 and N,N-dimethylformamide dimethyl acetal ( 3 ) or t-buthoxy-bis(dimethy1amino)methane (4), are transformed with 2-phenyl-5(4H)-oxazolone (1) into the corresponding intermediates 2, which cy