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C-13 magnetic resonance studies of some papaveraceae alkaloids

โœ Scribed by Thomas T. Nakashima; Gary E. Maciel


Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
871 KB
Volume
5
Category
Article
ISSN
0749-1581

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โœฆ Synopsis


Abstract

The natural abundance ^13^C magnetic resonance spectra of some Papaveraceae alkaloids have been determined at 22ยท628 MHz employing the pulse Fourier transform technique. Several techniques were employed to aid in spectral assignments and it has been possible to make selfโ€consistent assignments for all the resonances for these alkaloids. Evidence is presented for transโ€annular interaction between the amino group and the carbonyl group situated across the tenโ€membered ring.


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