Butane-1,4-diammonium decavanadate(V) hexahydrate
✍ Scribed by Rakovský, Erik ;Gyepes, Robert
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 282 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The asymmetric unit cell of the title compound, (C 4 H 14 N 2 ) 3 -[V 10 O 28 ]Á6H 2 O, consists of one half-decavanadate anion of C i symmetry, three water molecules, one butane-1,4-diammonium cation in a general position and one half-butane-1,4diammonium cation in a special position of C i symmetry. Water molecules are located within cavities of a framework formed by the anions and cations. All molecules are connected via hydrogen bonds into a three-dimensional network.
metal-organic papers m2110 Rakovsky ´and Gyepes (C 4 H 14 N 2 ) 3 [V 10 O 28 ]Á6H 2 O
📜 SIMILAR VOLUMES
The asymmetric unit of the title compound, (C 3 N 2 H 12 ) 3 -[V 10 O 28 ]Á5.5H 2 O, contains half each of two decavanadate ions, which lie on crystallographic inversion centres, two whole and two halves of doubly protonated propane-1,3-diammonium ions, and five and a half uncoordinated water molecu