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Bulky Chelating Diamide Complexes of Zirconium: Synthesis, Structure, and Reactivity of d 0 Alkyl Derivatives

✍ Scribed by Scollard, John D.; McConville, David H.; Vittal, Jagadese J.

Book ID
120479925
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
262 KB
Volume
16
Category
Article
ISSN
0276-7333

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Sterically Demanding Diamide Ligands: Sy
Sterically Demanding Diamide Ligands: Synthesis and Structure of d0 Zirconium Alkyl Derivatives
✍ Scollard, John D.; McConville, David H.; Vittal, Jagadese J. πŸ“‚ Article πŸ“… 1995 πŸ› American Chemical Society 🌐 English βš– 399 KB

The chelating diamide complexes (BDAPIZr-(NMed2 (21, (BDAP)ZrClz(pyh (4), (BDAP)ZrR2 (5a, R = CH2Ph; 5b, R = Me), (BDAP) Zr(l;15-Cp)C1 (5c), and(BDAP)Zr(rl2(N,C)-NC5H4)(CH2CMe2Ph) (5d) (BDAP = ArNCH2CH2CHJLAr; Ar = 2,6-iPr~-Cd-€3) have been prepared. An X-ray study of (BDAP)Zrf$(N,C)-NC5H4)-( CH2CMe