## Synopsis The sedimentation coefficient sN of the DNA topoisomer with the linking number N is evaluated as a function of N and chain length on the basis of a (circular) twisted wormlike chain, i.e., a special case of the helical wormlike chain. Evaluation is carried out by an application of the
Brownian motion of the wormlike chain and segmental diffusion of DNA
β Scribed by Otto G. Berg
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1979
- Tongue
- English
- Weight
- 664 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0006-3525
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
The dynamics of the wormlike chain model for a polymer in solution is investigated in the case of free torsional and no longitudinal variations. A Langevin equation is derived and solved for circularly closed chains, neglecting hydrodynamic interactions. The local diffusion behavior of particular segments is described, and it is found that the meanβsquare displacements are proportional to t^3/4^ at short times. Also, the equilibrium correlation functions for the closed chain are derived from the dynamic model in both the discrete and wormlike cases.
π SIMILAR VOLUMES
The configurational properties of an isotropically bendable wormlike chain have been investigated using a Monte Carlo approach. In particular, radial distributions for endtoend separation, ring closure probabilities, and the angular correlation of the two ends of the chain have all been determined a
## Abstract The torsional energy of a DNA is the energy involved when the average angle between adjacent base pairs is modified under applied constraints. A relationship is established between the energy of superhelix formation of a upercoiled DNA and its torsional energy. This relationship, valid