Bromination of silatranyl-, germatranyl-, silyl-, and germyl-phenylacetylenes
✍ Scribed by Anastasia A. Selina; Sergey S. Karlov; Ekaterina V. Gauchenova; Andrei V. Churakov; Lyudmila G. Kuz'mina; Judith A. K. Howard; Jörg Lorberth; Galina S. Zaitseva
- Book ID
- 102232221
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 406 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1042-7163
- DOI
- 10.1002/hc.10211
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✦ Synopsis
with bromine, tetra-n-butylammonium tribromide (TBAT), and N-bromosuccinimide (NBS)/DMSO were investigated. The Z,E-ratio of isomeric dibromoalkenes formed in bromination reaction with Br 2 and TBAT are discussed. The crystal structures of N(CH 2 -CH 2 O) 3
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## The reaction of pivaloylethoxyacetylene with silicon halides, which has been found to occur as a 1,4-addition, leads to allenic ethers, which readily eliminate ethyl halides and are converted to previously unknown types of ketenes-stable element-substituted acylketenes. Gerrnanium-substituted acy
Neurotropic and antitumor activities of the pyridyl-substituted 5-Si(Ge)-isoxazolines and (3alkyl-4-triphenylgermylisoxazolin-2-yl)-5-carboxylic acid ethyl esters have been investigated. It has been shown that silylisoxazolin-2-yl derivatives are more potent in protection against hypoxia and Corazol