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Bromination of cyclopropanes using potassium bromide and cerium(IV) ammonium nitrate (CAN): synthesis of 1,3-dibromides

โœ Scribed by Vijay Nair; Sreeletha B. Panicker; Sindhu Mathai


Book ID
111759642
Publisher
Springer Netherlands
Year
2003
Tongue
English
Weight
73 KB
Volume
29
Category
Article
ISSN
0922-6168

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The reaction of dipolarophiles (several alkenes and alkynes) with ammonium cerium(IV) nitrate ((NH 4 ) 2 Ce(NO 3 ) 6 , CAN(IV)) in acetone under reflux gave 3-acetylisoxazole derivatives. In the case of acetophenone, 3-benzoylisoxazole derivatives were obtained. Moreover, it was found that yields of