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Bromination of barbaralone; a new route to triasteranes

✍ Scribed by E. Vedejs

Book ID
104240206
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
186 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis

In connection with our interest in bicyclic organopalladium complexes (l), we required halogenated derivatives of bicyclo[3.3.1 I-nonadien-g-one. The simplest route to such compounds appeared to be via halogenation of barbaralone, by analogy to the bromination of other bridged homotropilidenes (2). The major product, however, proved to be a substituted triasterane, while the expected bicyclic dibromides accounted for only 15% of the products.

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